Module Specifications.
Current Academic Year 2024 - 2025
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Date posted: September 2024
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Repeat examination |
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Description To introduce the basic aspects of coordination chemistry and ligand field theory. To introduce the concept of symmetry and its effect on spectroscopy. To introduce main group chemistry. To provide examples of the application of inorganic chemistry in industry. | |||||||||||||||||||||||||||||||||||||||||||
Learning Outcomes 1. Have a comprehensive overview of coordination chemistry 2. Explain with the aid of examples main group chemistry 3. Know the importance of symmetry | |||||||||||||||||||||||||||||||||||||||||||
All module information is indicative and subject to change. For further information,students are advised to refer to the University's Marks and Standards and Programme Specific Regulations at: http://www.dcu.ie/registry/examinations/index.shtml |
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Indicative Content and Learning Activities
Transition Metal Chemistry.Introduction to crystal field theory; splitting of 'd' energy levels in octahedral, tetrahedral and square planar complexes; 10Dq and the spectrochemical series; high and low spin complexes; magnetic properties; Oxidation states and reaction chemistry of the elements and their compounds; Classical complexes, including a discussion of coordination number, nomenclature and isomerism. Survey of transition metal elements, first, second and third row transition elements.Main Group ChemistryGroup 13 Halides, oxides, nitrogen compounds, borates and borides, organometallic compounds; Group 14 Simple compounds; carbides; silicates and silicones; stability of the +2 oxidation state; catenation; organo metallic compounds. Group 15 Oxides, halides and sulphur compounds of nitrogen and phosphorus; acids and phosphates; nitrides.Molecular Shape and SymmetryVSEPR concept; symmetry elements; introduction to point groups for describing molecular geometry, point groups in infrared spectroscopy. | |||||||||||||||||||||||||||||||||||||||||||
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Indicative Reading List
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Other Resources None | |||||||||||||||||||||||||||||||||||||||||||